PowerShell grants access to your certificate stores by using the cert: drive.
You can use this drive to find certificates based on given criteria. This would list all certificates that have a date in NotAfter that is before today (indicating expired certificates):
$today = Get-Date Get-ChildItem -Path cert:\ -Recurse | Where-Object { $_.NotAfter -ne $null } | Where-Object { $_.NotAfter -lt $today } | Select-Object -Property FriendlyName, NotAfter, PSParentPath, Thumbprint | Out-GridView