Sure you can use the command net use to map a network drive. But this would not check for existing mapped drives. Here's a small function that first checks to see that the URL you are mapping to does not yet exist, avoiding duplicate mapped drives:
function New-MapDrive { param($Path) $present = @(Get-WmiObject Win32_Networkconnection | Select-Object -ExpandProperty RemoteName) if ($present -contains $Path) { "Network connection to $Path is already present" } else { net use * $Path } }